Crucible aperture: an effective way to reduce source oxidation in oxide molecular beam epitaxy process

Growing multi-elemental complex-oxide structures using an MBE (Molecular Beam Epitaxy) technique requires precise control of each source flux. However, when the component elements have significantly different oxygen affinities, maintaining stable fluxes for easily oxidizing elements is challenging because of a source oxidation problem. Here, using Sr as a test source, we show that a crucible aperture insert scheme significantly reduces the source oxidation in an oxide-MBE environment. The crucible aperture insert was shaped like a disk with a hole at the center and was mounted inside the crucible; it blocks most of the oxygen species coming to the source, thus reducing the source oxidation. However, the depth of the aperture disk was critical for its performance; an ill-positioned aperture could make the flux stability even worse. With an optimally positioned aperture insert, the crucible exhibited more than four times improvement in Sr flux stability, compared to a conventional, non-apertured crucible.Comment: 13 pages, 3 figure

Conformations and charge transport characteristics of biphenyldithiol self-assembled-monolayer molecular electronic devices: A multiscale computational study

We report a computational study of conformations and charge transport characteristics of biphenyldithiol (BPDT) monolayers in the (sqrt(3)×sqrt(3))R30° packing ratio sandwiched between Au(111) electrodes. From force-field molecular-dynamics and annealing simulations of BPDT self-assembled monolayers (SAMs) with up to 100 molecules on a Au(111) substrate, we identify an energetically favorable herringbone-type SAM packing configuration and a less-stable parallel packing configuration. Both SAMs are described by the (2sqrt(3)×sqrt(3))R30° unit cell including two molecules. With subsequent density-functional theory calculations of one unit cell of the (i) herringbone SAM with the molecular tilt angle theta[approximate]15°, (ii) herringbone SAM with theta[approximate]30°, and (iii) parallel SAM with theta[approximate]30°, we confirm that the herringbone packing configuration is more stable than the parallel one but find that the energy variation with respect to the molecule tilting within the herringbone packing is very small. Next, by capping these SAMs with the top Au(111) electrode, we prepare three molecular electronic device models and calculate their coherent charge transport properties within the matrix Green's function approach. Current–voltage (I–V) curves are then obtained via the Landauer–Büttiker formula. We find that at low-bias voltages (|V|~0.5 V), the I–V characteristics of the three models show noticeable differences due to different phenyl band structures. We thus conclude that the BPDT SAM I–V characteristics in the low-bias voltage region are mainly determined by the Si–Au interaction within the individual molecule-electrode contact, while both intramolecular conformation and intermolecular interaction can affect the BPDT SAM I–V characteristics in the high-bias voltage region

Possible performance improvement in [2]catenane molecular electronic switches

Mechanically interlocked bistable supramolecular complexes are promising candidates of molecular electronics. Applying a multiscale computational approach, here we study the coherent charge transport properties of catenane monolayers sandwiched between Cu(111) electrodes. We demonstrate the robust nature of electrical switching behavior with respect to the variations in the monolayer packing density and the type of electrodes, as well as the thermal fluctuations of the molecules. We propose that the asymmetry of molecule-electrode barriers can be utilized to improve the switching ratio

Batalin-Tyutin Quantization of the Chiral Schwinger Model

We quantize the chiral Schwinger Model by using the Batalin-Tyutin formalism. We show that one can systematically construct the first class constraints and the desired involutive Hamiltonian, which naturally generates all secondary constraints. For $a>1$, this Hamiltonian gives the gauge invariant Lagrangian including the well-known Wess-Zumino terms, while for $a=1$ the corresponding Lagrangian has the additional new type of the Wess-Zumino terms, which are irrelevant to the gauge symmetry.Comment: 15 pages, latex, no figures, to be published in Z. Phys. C (1995

On the sandstorms and associated airborne dustfall episodes observed at Cheongwon in Korea in 2005

Sandstorms in the desert and loess regions of north-northwestern China and Mongolia, as well as the associated dustfall episodes in the Korean Peninsula, were monitored between January and December 2005. Composite color images were made on the basis of data received directly from the National Oceanic and Atmospheric Administration satellite advanced very high resolution radiometer, and the distribution and transport of dust clouds were analyzed. The ground concentrations of PM10 and PM2.5 and visibility during dustfall episodes (where the PM10 concentration exceeds 190 μg m−3 for at least 2 h) were also analyzed at Cheongwon, in central South Korea, which lies in the leeward direction from the origin of sandstorms. Fewer strong sandstorms occurred in the places of origin in 2005, mainly because of the snow cover with moderate high and low pressure systems in the place of dust origin. The weather patterns explain why there were fewer dustfall episodes in Korea in 2005 than in the period between 1997 and 2004. A total of seven dustfall episodes were monitored in Korea in 2005 and they covered a period of 11 days. In the summer of 2005, sandstorms occurred less frequently in the source region due to high humidity and weaker winds; as a result, there were no dustfall episodes in Korea. When the sandstorms at the source headed directly to Korea without passing through any large cities or industrial areas of China, the PM2.5 concentrations were up to 20% of the PM10 concentrations. However, when the sandstorms headed to Korea via the industrial areas of eastern China, where they pick up anthropogenic air pollutants, the PM2.5 concentrations were at least 25% of the PM10 concentrations. In five of the cases that were observed and analyzed in 2005, the PM10 concentrations of the sand dust that originated in the deserts were 190 μg m−3 or less, which is below the level of a dustfall episode